However, both equations cannot be explicitly solved, meaning approximation methods have to be employed. Is known, the intrinsic viscosity can be calculated. Both Ĭoncentration but depend on the polymer-solvent system. Usually expressed in grams per 100 cm 3 or in grams per dl. Respectively, and c is the polymer concentration, Reduced specific viscosity of polymer solutions as a function ofĬoncentration are the Huggin's and Martin's equation for dilute to moderately concentrated solutions, 1,2Īnd η sp are the intrinsic viscosity and the Two common equations that are frequently used to estimate the Thus, different relationships have been proposed for dilute andĬoncentrated polymer solutions. With each other, first through long range hydrodynamic interactions, and then byĪctual contacts, entanglements, aggregates, and finally by a network of physical crosslinks. In general, the relationship between viscosity and concentration becomes more complicated when the polymerĬoncentration increases, because the polymer chains start to interact The polymer -solvent system, that is on the type and structure of the polymer, its molecular weight and the The relationship between viscosity and concentration depends on The literature that has been analyzed by many scientists. Today, a huge amount of data can be found in Understanding the effect of macromolecular structure on the dynamics The viscosity of dilute and concetrated polymer solutions hasīeen studied for many decades and has played an important role in
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